The fastest way is to view the clip full screen mode, hit PrintScreen at the scene you want the screenshot of, open it in Paint Shop Pro, and resize it.
I used to create tons of movie galleries and found a program a few months ago called Magic Media ++ on www.download.com - It has a pretty slick interface and can resize mpeg and avi thumbs based on your requirements. Also, it grabs the first frame of the movie, but it has the option to set a different frame from within the movie based on your selection.
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