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Ozone is the main eye-, nose-, throat-, and lung-irritating gas in "photochemical smog."
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From
http://www.fredbortz.com/askozone.htm
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These free radicals then react with ozone in a catalytic chain reaction which destroys the ozone, but regenerates the free radical, allowing it to participate in additional reactions.
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From
http://en.wikipedia.org/wiki/Free_radical
(read the bottom regarding biology)
Then ask yourself if you want a machine producing ozone in your home.