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Too many to name but as far as amazing straight up hard rock songs, these come to mind (maybe I'm just conventional):
Zepplin - black dog (or rock n roll)
Sabbath - Paranoid
Hendrix - Purple Haze
GnR - Welcome to the jungle
AC/DC - Thunderstruck
I'd have a very different list for ballads and best metal songs (yes Sabbath is metal but paranoid is hard fast rock IMO).
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