There are a handful of songs that can quickly get a rise out of me - Bryan Feerry's "Slave to Love" and Joe Cocker's "You can leave you hat on" come to mind.
But this song always did it for me.
I hope this isn't a repost, but this video is smoking hot:
http://www.dudemannews.com/media_pages/jessica_simpon_s_these_boots_are_made_for_walkin_. php