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Physical laws are a set of rules also. I'm not sure this rescues free will.
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True, physical laws that are on the molecular and atomic level are based on rigid laws but as you said anything smaller than that is kind of a mystery and not well understood just yet.
I believe even in the Physical laws of things such as Quarks, time and such there is randomness, hence our vast and abundant universe. I doubt that everything was preconceived
Everything is based on rules but the randomness of the application of the rules result in free will.