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make sure they are on the same subnets...i.e. both on 192.168.0.*, not one on 192.168.1.* and the other on 192.168.0.*.
make sure you have the firewall turned off on the XP machine....this means any program like zone alarm or norton internet security, AND the built in SP1 firewall (disable it in network settings).
This method works...I use it all the time to sync my powerbook and windows machines. If it is not working, it is because you have something blocking it.
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