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do you want to center it on the main background? just click the main background layer. then click the link icon next to the layer you want to center. go to the move tool (top right of the toolbox) click it then look for icons along the top of the interface you should see one with several boxes with a line through them. click the one with the line through the center of the boxes. it will center the linked layer to the master layer you originally selected.
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