I really like
http://www.lynda.com/ for learning programs.
I learned web stuff on Macromedia products. I had to do a CDROM project in Photoshop/Illustrator.
I used the $25/mo online access and saved every movie tutorial then watched them when I had the time- or as needed.
It got me up and running as quickly as possible.
Don't think you can go wrong with their books/CDROMs/Online vids.