Photoshop is not made for Vector Graphics, nor is that the standard. The reason the recommend it is because it is of higher quality for...shirts and shit like that. It CAN be done in photoshop anyways but is pretty crappy. Use Illustrator instead.
Use the Pen Tool in PS to get vectors.
Make a selection go to Paths ( next to Layers and Channels most of the time ) go to the arow on the right and select MAKE WORKPATH and then select and see if thaz good enough for U.
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