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You should set the color profile assigned to your monitor first.. then launch photoshop and use one the presets or your fave calibrated color setup.
If you work for the web, you'd start to work in RGB and even better use the web safe palette or swatches from the very beginning.
Same can happen when someone imposrt vector drawings, logos ertc. with CMYK presets, all colors are messed up.
hth
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