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The best resolution you will get from a DVD is 504x744 (or something like this). This Apple program seems to be fine, but I guess it's ashit load of work to prepare the photos.
The best will be you do the screen caps of the DVD by hand. Take a scene without a lot of moving in there, so you will get the best results. I usually use WinDVD and the results are ok.
When you liek to take a screen cap, push the pause button and move on frame by frame until you will get the best picture on the screen.
The other way to work around this, will be like encode the dvd into avi very high resolution (uncompressed) and encode it to JPG (per frame 2 photos). Then throw out the stuff you do not like, but I think this will take a lot of disk space and time either
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