Did you sign up for the account with an existing username? People have done test sales with them before and gotten hung up on that particular sticking point. If the account already exists as a gratis account for an affiliate, it won't "pay out" again to another webmaster, even with a different credit card.
I've worked with SexKey since the 90's, and I can tell you with certainty that they've passed every test I've ever thought I had to put them through.
In the late 90's and early 2000's, my house, my cars, my boat ... all SexKey.
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