twoplustwo is definitely the place to start reading. Especially check out the FAQ's in their stickies. There's some incredibly good reading in there.
To play completely free, partypoker.net has some pretty big tournaments starting every hour. All the major sites have some play money tables. Playing the free games is not the same as when money is involved though, obviously. You can learn a lot of general things from the free tournaments, but you'll definitely need to make adjustments against players who are going for real money.
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