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It happened to my german sherperd up in Northern Arizona.
We had fortunately just watched a show of "Myth Busters" and the solution was outstanding.
They compared tomato juice to the skunk products and then to a doctors recommendation and found the best solution is the following:
Gallon of Hydrogen peroxide mixed with as much baking soda as you get from a store.
It will lift the oils out of the skin. Get rid of the collar immediately as there is no way to get it out, and put your dog in the garage, as ours was very sick for 24 hours.
Best of luck. It was a long night for us, but it does go away.
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