You might also want to consider ruby and python if you are looking to learn something new for yourself. Much easier to learn than both php and asp. They both also usually require much less code to get the same tasks done. Especially with ruby on rails. You usually also end up writing much cleaner code that is also more understandable. Especially with python.
To answer your question though, .net if your looking for a job(like someone mentioned), php if your looking to make your own scripts.
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