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Linked-tables infrastructure (PMA Database) has nothing to do with your problem. Linked-tables is the feature of phpMyAdmin with which you can leave comments for tables and field columns as well as pull data with foreign keys from several tables for visual disply only through phpmyadmin interface.
problem lays somewhere outside of phpmyadmin scripts, in actual scripts that used for registration, as woj said probably something with mail config in those scripts, but its impossible to tell anything from that error your getting.
this could also be if you're on a shared hosting and local smtp server is out of your reach or simply disabled, again this is just a guess.
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