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Since I am a family man, late nights work better for me as far as working on sites, pages, code, etc.. but for business that involves other people or companies that involve processors, content, hosting, designers, etc.. it all depends on their hours too, so, alot needs attention during daytime hours, as well as convenient hours in others timezones, etc..
this is a 24/7 job, but for me, I get most work done after 8pm when wife & child go to bed.
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