Originally Posted by justinsain

Why should the subject be centered in the picture frame?

It looks like she placed the subject in relation to the background and
not dead center of the frame. Look at the picture and imagine the model
moved to the center of the frame without changing the camera angle.
Do you think that would have been better?

If she had placed the model in the center the model would have had
a building coming out the top of her head and the hair light wouldn't have
been nearly as effective.

Typically the eye looks at a photograph left to right much like when reading
text on a page unless there is someting " eye catching " that draws the viewer directly to it. There is nothing wrong with placing the main subject off center and especially to the right as long as there is something to fill the space and in this case the background does that.